cybertect
It's grim up north (London)
FWIW, my workflow starts with Adobe Camera RAW and I convert directly to sRGB, which is my working colour space in Photoshop. Since most of my photos are targeted for the web or printing via drivers that work in sRGB, I'm prepared to put up with the smaller colour space compared with Adobe RGB. Final files for the web are saved with an sRGB tag.
I'm wondering slightly about your mention of assigning, not converting colour spaces earlier in the thread. AFAIK, assignment just maps to the target colour space without any reference to the source space and should only really be used when dealing with untagged files, or if the tagged version is unsatisfactory and you're (randomly) fishing around for something better. Assign a colour profile to a previously tagged file and you'll probably get unexpected results.
When working with sRGB files, I'd expect non-colour managed applications on Windows to use that as their default colour space, so you should see little or no difference between an untagged and sRGB tagged file in those.
It might also be worth reading Microsoft's notes on the subject under XP
http://www.microsoft.com/windowsxp/using/digitalphotography/prophoto/colorspaces.mspx
I'm wondering slightly about your mention of assigning, not converting colour spaces earlier in the thread. AFAIK, assignment just maps to the target colour space without any reference to the source space and should only really be used when dealing with untagged files, or if the tagged version is unsatisfactory and you're (randomly) fishing around for something better. Assign a colour profile to a previously tagged file and you'll probably get unexpected results.
When working with sRGB files, I'd expect non-colour managed applications on Windows to use that as their default colour space, so you should see little or no difference between an untagged and sRGB tagged file in those.
It might also be worth reading Microsoft's notes on the subject under XP
http://www.microsoft.com/windowsxp/using/digitalphotography/prophoto/colorspaces.mspx
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