and which precise law / laws of thermodynamics does it violate? and how does it violate them?
bit hard to argue against with such a vague statement... oh, wait that's how bigfish operates isn't it
Here you go Dr spirit (how's your quest for the illusive CO2 driver theory going by the way, any luck yet?):
Listed papers below available to read here:
http://www.gasresources.net/toc_StatMech.htm
1.
The Constraints of the Laws of Thermodynamics upon the Evolution of Hydrocarbons: The Prohibition of Hydrocarbon Genesis at Low Pressures.
J. F. Kenney, I. K. Karpov, Ac. Ye. F. Shnyukov, V. A. Krayushkin, I. I. Tchebanenko, V. P. Klochko, (2001), Energia, 22/3, 18-23. PDF version.
2.
Dismissal of Claims of a Biological Connection for Natural Petroleum.
J. F. Kenney, Ac. Ye. F. Shnyukov, V. A. Krayushkin, I. K. Karpov, V. G. Kutcherov, I. N. Plotnikova, (2001), Energia, 22/3, 26-34. PDF version.
3.
The Evolution of Multicomponent Systems at High Pressures: VI. The Thermodynamic Stability of the Hydrogen-Carbon System: The Genesis of Hydrocarbons and the Origin of Petroleum.
J. F. Kenney, V. G. Kutcherov, N. A. Bendeliani, V. A. Alekseev, (2002), Proceedings of the National Academy of Sciences (U.S.A.), 99/17, 10976-10981. PDF version
4.
The synthesis of hydrocarbons from abiotic reagents at pressures to 5 Gpa.
V. G. Kutcherov, N. A. Bendeliani, V. A. Alekseev, J. F. Kenney, (2002), Proceedings of the National Academy of Sciences of Russia, 387/6, 789-792. PDF version
5.
The Evolution of Multicomponent Systems at High Pressures: IV. The Genesis of Optical Activity in High-density, Abiotic Fluids.
J. F. Kenney, U. K. Deiters, (2001), Physical Chemistry - Chemical Physics, 2, 3163-3174. PDF version
6.
The Evolution of Multicomponent Systems at High Pressures: II. The Alder-Wainwright, High-Density, Gas-Solid Phase Transition of the Hard-Sphere Fluid.
J. F. Kenney, (1999), Physical Chemistry - Chemical Physics, 1, 3277-3285. PDF version
7.
The Evolution of Multicomponent Systems at High Pressures: I. The High-Pressure, Supercritical, Gas-Liquid Phase Transition.
J. F. Kenney, Fluid Phase Equilibria, (1998), 148, 21-47. PDF version.
8.
Development of a general equation of state for real molecules in arbitrary regimes of temperature and pressure: I. The hard-core reference system.
J. F. Kenney, R. J. Petti, (2005).
9.
The microcanonical thermodynamics of finite systems: The microscopic origin of condensation and phase separations, and the conditions for heat flow from lower to higher temperatures.
D. H. E. Gross and J. F. Kenney, (2005), J. Chem. Phys., 122, 1-8. PDF version